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camphor

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camphor[1][2]
Structural formula of (R) and (S)-camphor
Structural formula of (R) and (S)-camphor
(+)- and (−)-camphor
Ball and stick model of camphor (both enantiomers).
Ball and stick model of camphor (both enantiomers).
Names
IUPAC name
1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
Other names
2-Bornanone; Bornan-2-one; 2-Camphanone; Formosa
Identifiers
3D model (JSmol)
1907611
ChEBI
ChEMBL
ChemSpider
DrugBank
EC Number
  • 200-945-0
83275
KEGG
MeSH Camphor
RTECS number
  • EX1225000
UNII
UN number 2717
  • InChI=1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3 checkY
    Key: DSSYKIVIOFKYAU-UHFFFAOYSA-N checkY
  • InChI=1/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3
    Key: DSSYKIVIOFKYAU-UHFFFAOYAK
  • CC1(C)C2CCC1(C)C(=O)C2
  • O=C1CC2CCC1(C)C2(C)C
Properties
C10H16O
Molar mass 152.237 g·mol−1
Appearance White, translucent crystals
Odor Fragrant and penetrating
Density 0.992 g·cm−3
Melting point 175–177 °C (347–351 °F; 448–450 K)
Boiling point 209 °C (408 °F; 482 K)
1.2 g·dm−3
Solubility in acetone ~2500 g·dm−3
Solubility in acetic acid ~2000 g·dm−3
Solubility in diethyl ether ~2000 g·dm−3
Solubility in chloroform ~1000 g·dm−3
Solubility in ethanol ~1000 g·dm−3
log P 2.089
Vapor pressure 4 mmHg (at 70 °C)
+44.1°
−103×10−6 cm3/mol
Pharmacology
C01EB02 (WHO)
Hazards
GHS labelling:
GHS02: FlammableGHS07: Exclamation markGHS08: Health hazard
Warning
H228, H302, H332, H371
P210, P240, P241, P260, P261, P264, P270, P271, P280, P301+P312, P304+P312, P304+P340, P309+P311, P312, P330, P370+P378, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
2
0
Flash point 54 °C (129 °F; 327 K)
466 °C (871 °F; 739 K)
Explosive limits 0.6–3.5%[3]
Lethal dose or concentration (LD, LC):
1310 mg/kg (oral, mouse)[4]
800 mg/kg (dog, oral)
2000 mg/kg (rabbit, oral)[4]
400 mg/m3 (mouse, 3 hr)[4]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 2 mg/m3[3]
REL (Recommended)
TWA 2 mg/m3[3]
IDLH (Immediate danger)
200 mg/m3[3]
Related compounds
Related ketones
Fenchone, thujone
Related compounds
Camphene, pinene, borneol, isoborneol, camphorsulfonic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Főnév

camphor (tsz. camphors)

  1. (gyógyszertan) kámfor
  1. The Merck Index, 7th edition, Merck & Co., Rahway, New Jersey, 1960
  2. Handbook of Chemistry and Physics, CRC Press, Ann Arbor, Michigan, USA
  3. 1 2 3 4 NIOSH Pocket Guide to Chemical Hazards: #0096. National Institute for Occupational Safety and Health (NIOSH)
  4. 1 2 3 Camphor (synthetic). National Institute for Occupational Safety and Health (NIOSH), 2014. december 4. [2015. március 13-i dátummal az eredetiből archiválva].