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formaldehyde

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formaldehyde
Structural formula of formaldehyde (with hydrogens)
Structural formula of formaldehyde (with hydrogens)
Spacefill model of formaldehyde
Spacefill model of formaldehyde
Ball and stick model of formaldehyde
Ball and stick model of formaldehyde
Names
Preferred IUPAC name
Formaldehyde[1]
Systematic IUPAC name
Methanal[1]
Other names
  • Methyl aldehyde
  • Methylene glycol (diol forms in aqueous solution)
  • Methylene oxide
  • Formalin (aqueous solution)
  • Formol
  • Carbonyl hydride
  • Methanone
  • Oxomethane
  • Formic aldehyde
Identifiers
3D model (JSmol)
1209228
ChEBI
ChEMBL
ChemSpider
DrugBank
EC Number
  • 200-001-8
445
KEGG
MeSH Formaldehyde
RTECS number
  • LP8925000
UNII
UN number 2209
  • InChI=1S/CH2O/c1-2/h1H2 checkY
    Key: WSFSSNUMVMOOMR-UHFFFAOYSA-N checkY
  • InChI=1/CH2O/c1-2/h1H2
    Key: WSFSSNUMVMOOMR-UHFFFAOYAT
  • C=O
Properties[2]
CH2O
Molar mass 30.026 g·mol−1
Appearance Colorless gas
Density 0.8153 g/cm3 (−20 °C)[3] (liquid)
Melting point −92 °C (−134 °F; 181 K)
Boiling point −19 °C (−2 °F; 254 K)[3]
400 g/L
log P 0.350
Vapor pressure > 1 atm[4]
Acidity (pKa) 13.27 (hydrate)[5][6]
−18.6·10−6 cm3/mol
2.330 D[7]
Structure
C2v
Trigonal planar
Thermochemistry[8]
35.387 J·mol−1·K−1
218.760 J·mol−1·K−1
−108.700 kJ·mol−1
−102.667 kJ·mol−1
571 kJ·mol−1
Pharmacology
QP53AX19 (WHO)
Hazards
GHS labelling:
GHS06: ToxicGHS05: CorrosiveGHS08: Health hazard[9]
Danger
H301+H311+H331, H314, H317, H335, H341, H350, H370[9]
P201, P280, P303+P361+P353, P304+P340+P310, P305+P351+P338, P308+P310[9]
NFPA 704 (fire diamond)
Flash point 64 °C (147 °F; 337 K)
430 °C (806 °F; 703 K)
Explosive limits 7–73%
Lethal dose or concentration (LD, LC):
100 mg/kg (oral, rat)[10]
333 ppm (mouse, 2 h)
815 ppm (rat, 30 min)[11]
333 ppm (cat, 2 h)[11]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.75 ppm ST 2 ppm (as formaldehyde and formalin)[12][13]
REL (Recommended)
Ca TWA 0.016 ppm C 0.1 ppm [15-minute][12]
IDLH (Immediate danger)
Ca [20 ppm][12]
Safety data sheet (SDS) MSDS(Archived)
Related compounds
Related aldehydes
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Főnév

formaldehyde (tsz. formaldehydes)

  1. (gyógyszertan) formaldehid
  1. 1 2  
  2.  
  3. 1 2 SIDS Initial Assessment Report. International Programme on Chemical Safety. [2019. március 28-i dátummal az eredetiből archiválva].
  4.  
  5. PubChem Compound Database; CID=712. National Center for Biotechnology Information. [2019. április 12-i dátummal az eredetiből archiválva].
  6. Acidity of aldehydes. Chemistry Stack Exchange. [2018. szeptember 1-i dátummal az eredetiből archiválva].
  7. Selected Values of electric dipole moments for molecules in the gas phase (NSRDS-NBS10), 1967. [2018. június 8-i dátummal az eredetiből archiválva].
  8.  
  9. 1 2 3 Record of Formaldehyde in the GESTIS Substance Database of the Institute for Occupational Safety and Health, accessed on 13 March 2020.
  10. Substance Name: Formaldehyde [USP]. ChemlDplus . US National Library of Medicine. [2017. szeptember 18-i dátummal az eredetiből archiválva].
  11. 1 2 Formaldehyde. Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH)
  12. 1 2 3 NIOSH Pocket Guide to Chemical Hazards: #0293. National Institute for Occupational Safety and Health (NIOSH)
  13. NIOSH Pocket Guide to Chemical Hazards: #0294. National Institute for Occupational Safety and Health (NIOSH)